The Application of Alkali Activator and Admixture for High Early Concrete Compressive Strength with GGBFS Substitution
DOI:
https://doi.org/10.21831/inersia.v21i2.87887Keywords:
Alkali Activator, Ground Granulated Blast Furnace Slag, Cement, Compressive strength, ConcreteAbstract
Concrete with high early compressive strength is designed to reach at least 20 MPa within the first 24 hours after casting. However, achieving this generally requires increased cement content, which unfortunately leads to higher carbon emissions and production costs. To reduce this impact, cement can be partially substituted with pozzolans such as ground granulated blast furnace slag (GGBFS), which has a chemical composition similar to cement. Nevertheless, GGBFS exhibits a slow hydration process; therefore, an alkali activator is required to accelerate the reaction. On the other hand, alkali activation can reduce concrete workability, making the addition of admixtures such as superplasticizers necessary to maintain adequate workability. This study investigates the effect of adding alkali activators and admixtures on concrete's early compressive strength and workability of concrete incorporating GGBFS as a cement substitute. Ordinary Portland cement and GGBFS were used at a ratio of 70:30. The alkali activator consisted of NaOH and Na₂SiO₃, with a Na₂SiO₃/NaOH ratio (R) of 1.5 and a total alkali-to-GGBFS ratio (A) of 0.45. The superplasticizer was Sika® ViscoCrete®-1050 HE at at dosages of 0.5% and 1%. The alkali activator contents tested were 0%, 2.5%, 5%, 7.5%, and 10%. The paste-to-fine aggregate void ratio (Rm) and the mortar-to-coarse aggregate void ratio (Rb) were both set at 1.4. Workability was evaluated using the slump test, while compressive strength was measured at 24 hours. The results showed that the addition of an alkali activator led to a substantial improvement in the compressive strength of the concrete, reaching up to 114.8% of the minimum required early compressive strength. The compressive strength peaked at 43 MPa when 10% alkali activator was added to the mixture. However, increasing the alkali activator content significantly reduced workability, with the slump value reaching zero at the 10% dosage. The addition of a superplasticizer was proven to be necessary to maintain a balance between early strength and concrete workability.
References
[1] P. Ganesh and A. R. Murthy, “Tensile behaviour and durability aspects of sustainable ultra-high performance concrete incorporated with GGBS as cementitious material,” Constr Build Mater, vol. 197, pp. 667–680, Feb. 2019, doi: 10.1016/j.conbuildmat.2018.11.240.
[2] A. Ainie Mat Dom, N. Jamaluddin, N. Azlina Abdul Hamid, and C. Siok Hoon, “A Review: GGBS as a Cement Replacement in Concrete,” in IOP Conference Series: Earth and Environmental Science, Institute of Physics, May 2022. doi: 10.1088/1755-1315/1022/1/012044.
[3] A. A. Adam, “The Effects of Water to Solid Ratio, Activator to Binder Ratio, and Lime Proportion on the Compressive Strength of Ambient-Cured Geopolymer Concrete,” Journal of the Civil Engineering Forum, vol. 5, no. 2, p. 161, May 2019, doi: 10.22146/jcef.43878.
[4] “Specification for Labeling of End Items that Incorporate Plastics and Polymers as Coatings or Additives with Paper and Other Substrates Designed to be Aerobically Composted in Municipal or Industrial Facilities,” Feb. 01, 2021, ASTM International, West Conshohocken, PA. doi: 10.1520/D6868-21.
[5] M. Jafari Nadoushan and A. A. Ramezanianpour, “The effect of type and concentration of activators on flowability and compressive strength of natural pozzolan and slag-based geopolymers,” Constr Build Mater, vol. 111, pp. 337–347, May 2016, doi: 10.1016/j.conbuildmat.2016.02.086.
[6] I. Phummiphan, S. Horpibulsuk, R. Rachan, A. Arulrajah, S. L. Shen, and P. Chindaprasirt, “High calcium fly ash geopolymer stabilized lateritic soil and granulated blast furnace slag blends as a pavement base material,” J Hazard Mater, vol. 341, pp. 257–267, 2018, doi: 10.1016/j.jhazmat.2017.07.067.
[7] Guide to the Use of Slag Cement in Concrete and Mortar. 2017. [Online]. Available: www.concrete.org
[8] P. Ananyachandran and V. Vasugi, “Development of a sustainable high early strength concrete incorporated with pozzolans, calcium nitrate and triethanolamine: An experimental study,” Sustainable Energy Technologies and Assessments, vol. 54, Dec. 2022, doi: 10.1016/j.seta.2022.102857.
[9] A. T. Yudhistira, I. Satyarno, A. S. B. Nugroho, and T. N. Handayani, “Effect of Construction Delays and the Preventive Role of Concrete Works Optimization: Systematic Literature Review,” TEM Journal, vol. 13, no. 2, pp. 1203–1217, May 2024, doi: 10.18421/TEM132-34.
[10] A. K. Yasin, R. Bayuaji, and T. E. Susanto, “A review in high early strength concrete and local materials potential,” in IOP Conference Series: Materials Science and Engineering, Institute of Physics Publishing, Nov. 2017. doi: 10.1088/1757-899X/267/1/012004.
[11] A. Aghaeipour and M. Madhkhan, “Effect of ground granulated blast furnace slag (GGBFS) on RCCP durability,” Constr Build Mater, vol. 141, pp. 533–541, Jun. 2017, doi: 10.1016/j.conbuildmat.2017.03.019.
[12] E. Özbay, M. Erdemir, and H. I. Durmuş, “Utilization and efficiency of ground granulated blast furnace slag on concrete properties - A review,” Feb. 15, 2016, Elsevier Ltd. doi: 10.1016/j.conbuildmat.2015.12.153.
[13] F. A. Shilar, S. V. Ganachari, V. B. Patil, T. M. Y. Khan, and S. Dawood Abdul Khadar, “Molarity activity effect on mechanical and microstructure properties of geopolymer concrete: A review,” Case Studies in Construction Materials, vol. 16, Jun. 2022, doi: 10.1016/j.cscm.2022.e01014.
[14] A. A. Aliabdo, A. E. M. Abd Elmoaty, and M. A. Emam, “Factors affecting the mechanical properties of alkali activated ground granulated blast furnace slag concrete,” Constr Build Mater, vol. 197, pp. 339–355, Feb. 2019, doi: 10.1016/j.conbuildmat.2018.11.086.
[15] S. Narimani Zamanabadi, S. A. Zareei, P. Shoaei, and F. Ameri, “Ambient-cured alkali-activated slag paste incorporating micro-silica as repair material: Effects of alkali activator solution on physical and mechanical properties,” Constr Build Mater, vol. 229, Dec. 2019, doi: 10.1016/j.conbuildmat.2019.116911.
[16] D. E. Angulo-Ramírez, R. Mejía de Gutiérrez, and F. Puertas, “Alkali-activated Portland blast-furnace slag cement: Mechanical properties and hydration,” Constr Build Mater, vol. 140, pp. 119–128, Jun. 2017, doi: 10.1016/j.conbuildmat.2017.02.092.
[17] R. Amar, R. Devanand, H. N. Harsha, and K. C. Sachin, “Experimental studies on GGBS based geopolymer concrete,” Mater Today Proc, 2023, doi: 10.1016/j.matpr.2023.04.297.
[18] J. Ahmad et al., “A Comprehensive Review on the Ground Granulated Blast Furnace Slag (GGBS) in Concrete Production,” Sustainability (Switzerland), vol. 14, no. 14, Jul. 2022, doi: 10.3390/su14148783.
[19] A. A. El-Gindy, M. M. El-Tonsy, H. I. Abdelkader, A. Mohsen, A. O. Habib, and E. A. Gomaa, “Comparative study on the environmental impact of Portland cement paste that mixed with naphthalene or carboxylate-based polymer solutions,” J Mol Liq, vol. 392, Dec. 2023, doi: 10.1016/j.molliq.2023.123164.
[20] M. J. de Hita and M. Criado, “Influence of admixtures on the workability and strength of sodium carbonate-activated slag/fly ash cement,” Mater Lett, vol. 312, Apr. 2022, doi: 10.1016/j.matlet.2022.131695.
[21] “Specification for Slag Cement for Use in Concrete and Mortars,” Dec. 15, 2018, ASTM International, West Conshohocken, PA. doi: 10.1520/C0989_C0989M-18A.
[22] R. Cornelis, H. Priyosulistyo, I. Satyarno, and Rochmadi, “The Investigation on Setting Time and Strength of High Calcium Fly Ash Based Geopolymer,” Applied Mechanics and Materials, vol. 881, pp. 158–164, May 2018, doi: 10.4028/www.scientific.net/amm.881.158.
[23] M. Putri, I. Satyarno, and D. Sulistyo, “Pengaruh Penambahan Borax terhadap Setting Time Pasta Geopolymer Berbahan Dasar Fly Ash dan Ground Granulated Blast Furnace Slag.”
[24] I. Satyarnoa, A. P. Solehudina, C. Meyartoa, D. Hadiyatmokoa, P. Muhammada, and R. Afnana, “Practical method for mix design of cement-based grout,” in Procedia Engineering, Elsevier Ltd, 2014, pp. 356–365. doi: 10.1016/j.proeng.2014.12.194.
[25] “Standar Nasional Indonesia Cara uji slump beton ICS 91.100.30 Badan Standardisasi Nasional”.
[26] “SNI. Standar Nasional Indonesia Tata cara pembuatan dan perawatan spesimen uji beton di lapangan”. SNI 4810:2013.
[27] “Cara uji kuat tekan beton dengan benda uji silinder Badan Standardisasi Nasional,” 2011, [Online]. Available: www.bsn.go.id
[28] S. A. Wulan, I. Satyarno, and A. Saputra, “Mix Design of Self Compacting Concrete Based on Ultra High Compressive Strength Flow Mortar Mix,” 2018.
[29] M. Rathee, A. Misra, J. Kolleboyina, and S. K. Sarma P, “Study of mechanical properties of geopolymer mortar prepared with fly ash and GGBS,” in Materials Today: Proceedings, Elsevier Ltd, 2023, pp. 377–386. doi: 10.1016/j.matpr.2023.07.360.
[30] H. Mehdizadeh and E. Najafi Kani, “Rheology and apparent activation energy of alkali activated phosphorous slag,” Constr Build Mater, vol. 171, pp. 197–204, May 2018, doi: 10.1016/j.conbuildmat.2018.03.130.
[31] R. Cornelis, H. Priyosulityo, I. Satyarno, Rochmadi, and I. Rustendi, “Effect of the Mortar Volume Ratio on the Mechanical Behavior of Class CI Fly Ash-Based Geopolymer Concrete,” Civil Engineering Journal (Iran), vol. 8, no. 9, pp. 1920–1935, Sep. 2022, doi: 10.28991/CEJ-2022-08-09-012.
[32] Report on measurements of workability and rheology of fresh concrete. American Concrete Institute, 2008.
[33] I. Navarrete and M. Lopez, “Understanding the relationship between the segregation of concrete and coarse aggregate density and size,” Constr Build Mater, vol. 149, pp. 741–748, Sep. 2017, doi: 10.1016/j.conbuildmat.2017.05.185.
[34] I. Navarrete and M. Lopez, “Estimating the segregation of concrete based on mixture design and vibratory energy,” Constr Build Mater, vol. 122, pp. 384–390, Sep. 2016, doi: 10.1016/j.conbuildmat.2016.06.066.
[35] H. Y. B. Katman et al., “Workability, Strength, Modulus of Elasticity, and Permeability Feature of Wheat Straw Ash-Incorporated Hydraulic Cement Concrete,” Buildings, vol. 12, no. 9, Sep. 2022, doi: 10.3390/buildings12091363.
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