SYNTHESIS AND PERFORMANCE TEST OF CO-EEGDMA AS A CARRIER IN PHENOL TRANSPORT USING POLYMER INCLUSION MEMBRANE

Agung Abadi Kiswandono, Jursan Kimia FMIPA Universitas Lampung, Indonesia

Abstract


This study was aimed to synthesize the polymer as a carrier, i.e. copolymer (Eugenol-ethylene glycol dimethacrylate, EGDMA) or co-EEGDMA. The synthesis involving eugenol and EGDMA as a crosslinking agent was performed by polymerization using a boron trifl uoro diethyl ether catalyst. The synthesized polymer was then characterized using FTIR, SEM and H-NMR. Co-EEGDMA and two other compounds, namely polyvinyl chloride (PVC) and dibenzyl ether (DBE) as the components in the membrane making process were tested to be used for phenol transport. The components then were tested using Polymer Inclusion Membrane (PIM) method. The characterization results of co-EEGDMA show that eugenol polymerization using EGDMA crosslinking agent has been successfully synthesized. The results also show that the membrane containing the new compounds can be used for phenol transport in multiple times.


Keywords


co-EEGDMA; DBE; eugenol; PIM; PVC

Full Text:

PDF

References


Febriasari, A., Siswanta, D., Kiswandono, A.A., dan Aprilita, N.H. 2016. Evaluation of Phenol Transport Using Polymer Inclusion Membrane (PIM) with Polyeugenol as a Carrier. Jurnal Rekayasa Kimia dan Lingkungan. Vol. 11, No. 2, 99-106.

Baker, R.W., 2000, Membrane Technology and Application, Mc Graw-Hill, New York.

Delgado, J.J., Chen, X., Pérez-Omil, J.A., Rodríguez-Izquierdo, J.M., dan Cauqui, M.A., 2012, The Effect of Reaction Conditions on the Apparent Deactivation of Ce–Zr Mixed Oxides for the Catalytic Wet Oxidation of Phenol, Chatalys Today, 180, 25 – 33.

Huidong, Z., Biyu, W., Yanxiang, W.U., dan Qilong, R.E.N., 2009, Instability Mechanisms of Suppoeted Liquid Membrane for Phenol Transport, Chin. J. Chem. Eng., 17(5), 750 – 755.

Kandwal, P., Ansari, S.A., dan Mohapatra, P.K., 2011. Transport of Cesium Using Hollow Fiber Supported Liquid Membrane Containing Calix[4]arene-bis(2,3-naphtho)crown-6 as the Carrier Extractant: Part II. Recovery from Simulated High Level Waste and Mass Transfer Modeling, J. Membr. Sci., 384, 37 – 43.

Kiswandono, A.A., Siswanta, D., dan Aprilita, N.H., 2010, Studi Transpor Fenol dengan Menggunakan Membran Cair Polieugenol, Prosiding Seminar Nasional, FKIP Jurusan Kimia Universitas Sebelas Maret, Surakarta.

Kiswandono, A.A., Santosa, S.J., Siswanta, D., dan Aprilita, N.H., 2013, Extending the Life Time of Polymer Inclusion Membrane Containing Copoly(Eugenol-DVB) as Carrier for Phenol Transport,Indo. J. Chem., 13(3), 254-261.

Kiswandono, A. A., Siswanta, D., Aprilita, N. H., Santosa, S. J. (2012) Transport of phenol through inclusion polymer membrane (PIM) using copoly (eugenol-DVB) as membrane carriers, Indonesian Journal of Chemistry, 12(2), 105 – 112.

Kiswandono, A. A. (2014). Kajian Transpor Fenol Melalui Membran Berbasis Polieugenol Tertaut Silang Menggunakan metode Polymer Inclusion Membrane (PIM). Disertasi. Universitas Gadjah Mada, Yogyakarta

Malboubi, M., Gu, Y., dan Jiang, K., 2011, Characterization of surface properties of Glass Micropipettes using SEM Stereoscopic Technique, Microelectron Eng., 88, 2666 – 2670.

Malusis, M.A., Maneval, J.E., Barben, E.J., Shackelford, C.D., dan Daniels, E.R., 2010, Influence of Adsorption on Phenol Transport Through Soil–Bentonite Vertical Barriers Amended with Activated Carbon, J. Contam. Hydrol., 116, 58 – 72

Mohammadkhani, A., Malboubi, M., Anthony, C., dan Jiang, K., 2011, Characterization of Surface Properties of Ordered Nanostructures Using SEM Stereoscopic Technique, Microelectron Eng., 88, 2687 – 2690

Mozhdehvari, H., Tabatabaei, SM., dan Tajkhalili, A., 2009, Catalytic Ozonation of Phenol Occurring in Power Plants Oily, Waste Water 24th International Power System Conference.

Raut, D.R., Mohapatra, P.K., dan Manchanda, V.K., 2012, A Highly Efficient Supported Liquid Membrane System for Selective Strontium Separation Leading to Radioactive Waste Remediation, J. Membr. Sci., 390 – 391, 76 – 83.

Senturk, H.B., Ozdes, D., Gundogdu, A., Duran, C., dan Soylak, M., 2009, Removal of Phenol from Aqueous Solutions by Adsorption onto Organomodified Tirebolu Bentonite: Equilibrium, Kinetic and Thermodynamic Study, J. Hazard. Mater., 172, 353 – 362.

Silvianti, F., Siswanta, D., Aprilita, N.H., Kiswandono, A.A. 2017. Adsorption characteristic of iron onto Poly[eugenol-co-(divinyl benzene)] from Aqueous solution. Jurnal Natural. Vol. 17, No. 2. 108-117

Stevens, M.P., 2001, Kimia Polimer alih bahasa oleh Sopyan I., diterjemahkan, dari buku Polymer Chemistry an Introduction, Pradnya Paramita, Jakarta.

Tseng, R., Wu, K., Wu, F., dan Juang, R., 2010, Kinetic Studies on the Adsorption of Phenol, 4-Chlorophenol, and 2,4-Dichlorophenol from Water Using Activated Carbons, J. Environ. Management, 91, 2208 – 2214.

Zidi, C., Tayeb, R., Ali, M.B.S., dan Dhahbi, M., 2010, Liquid–liquid Extraction and Transport Across Supported Liquid Membrane of Phenol Using Tributyl Phosphate. J. Membr. Sci., 360, 334 – 340.




DOI: https://doi.org/10.21831/jps.v22i2.16857

Refbacks

  • There are currently no refbacks.




Copyright (c) 2018 Jurnal Penelitian Saintek

Creative Commons License
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

 p-ISSN: 1412-3991 || e-ISSN: 2528-7036

Indexed by:

     

View My Stats